Code reference · NEC 625.41; 625.42; 625.54
Biggest EV charger on a 100 A circuit
An existing 100 A circuit supports at most 80 A of continuous EV charging: 100 ÷ 1.25 = 80 A (the inverse of NEC 625.41's 125% continuous-load rule). At 240 V that is about 19.2 kW of charging power.
Set the charger to 80 A or less — most hardwired EVSEs have DIP switches or a commissioning app for exactly this. A charger factory-set higher than 80 A on this circuit is a code violation even if the breaker doesn't trip immediately; continuous loading at 100% of breaker rating is what the 80% rule exists to prevent.
Also verify the existing conductors: a 100 A breaker on old wiring doesn't guarantee the wire ampacity matches today's Table 310.16 values after derates, and receptacle-connected EVSE (NEMA 14-50) adds its own requirements — including GFCI protection for the receptacle in newer code cycles (625.54).
Run the numbers yourself
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More references: What breaker for a 16 A EV charger? (NEC 625) · What breaker for a 24 A EV charger? (NEC 625) · What breaker for a 32 A EV charger? (NEC 625) · What breaker for a 40 A EV charger? (NEC 625) · What breaker for a 48 A EV charger? (NEC 625) · What breaker for a 64 A EV charger? (NEC 625) · all 97 references